Органическая химия, стр. 20
Семьдесят четвертый номер брошюры «Органический синтез» содержит описания следующих соединений: (-)-2-0-BENZYL-L-GLYCER ALDEHYDE AND ETHYL (R,E)-4-0-BENZYL-4.5-DIHYDROXY-2-PENTENOATE; ACETYLENIC ETHERS FROM ALCOHOLS AND THEIR REDUCTION TO Z- AND E-ENOL ETHERS: PREPARATION OF 1-MENTHOXY-1-BUTYNE FROM MENTHOL AND CONVERSION TO (Z)- AND (E)-1 -MENTHOXY-1 –BUTENE; (R)-(+)-2-(DIPHENYLHYDROXY-METHYL)PYRROLIDINE; (R)-(-)-2,2-DIPHENYLCYCLO-PENTANOL; (S)-TETRAHYDRO-1-METHYL-3,3-DIPHENYL-1 H,3H-PYRROLO[1,2c]-[1,3,2]OXAZABOROLE-BORANE COMPLEX; 1,2,3-TRIPHENYLCYCLOPROPENIUM BROMIDE; PYRIDINE-DERIVED TRIFLATING REAGENTS: N-(2-PYRIDYL)TRIFLIMIDE AND N-(5-CHLORO-2-PYRIDYL)-TRIFLIMIDE; BIS(TRIMETHYLSILYL) PEROXIDE (BTMSPO); SYNTHESIS OF EPOXIDES USING DIMETHYLDIOXIRANE: trans-STILBENE OXIDE; PREPARATION A...
2.6М, ENG.
Семьдесят третий номер брошюры «Органический синтез» содержит описания следующих соединений: 3-[(1S)-1,2-DIHYDROXYETHYL]-1,5-DIHYDRO-3H-2.4-BENZO-DIOXEPINE; 1 R,5S)-(-)-6,6-DIMETHYL-3-OXABICYCLO[3.1.0]HEXAN-2-ONE. HIGHLY ENANTIOSELECTIVE INTRAMOLECULAR CYCLO-PROPANATION CATALYZED BY DIRHODIUM(II) TETRAKIS[METHYL 2-PYRROLIDONE-5(R)-CARBOXYLATE]; ENANTIOSELECTIVE HYDROLYSIS OF cis-3,5-DIACETOXYCYCLO-PENTENE: (1R,4S)-(+)-4-HYDROXY-2-CYCLOPENTENYL ACETATE; (4R)-(+)-tert-BUTYLDIMETHYLSILOXY-2-CYCLOPENTEN-1 –ONE; (4S)-(-)-tert-BUTYLDIMETHYLSILOXY-2-CYCLOPENTEN-1-ONE; STEREOSELECTIVE ALKENE SYNTHESIS via 1-CHLORO-1-t(DIMETHYL)PHENYLSILYL]ALKANES] and a-(DIMETHYL)PHENYLSILYL KETONES: 6-METHYL-6-DODECENE; SYNTHESIS OF p-LACTONES AND ALKENES via THIOL ESTERS: (E)-2,3-DIMETHYL-3-DODECENE; ALKYLIDENAT...
2.6М, ENG.
Семьдесят второй номер брошюры «Органический синтез» содержит описания следующих соединений: L-(S)-GLYCERALDEHYDE ACETONIDE; D-(R)-GLYCERALDEHYDE ACETONIDE; (3S,4S)-3-AMINO-1 -(3,4-DIMETH-OXYBENZYL)-4-[(R)-2,2-DIMETHYL-1,3-DlOXOLAN-4-YL]-2-AZETIDINONE; DIASTEREOSELECTIVE HOMOLOGATION OF D-(R)-GLYCERALDEHYDE ACETONIDE USING 2-(TRIMETHYLSILYL)-THIAZOLE: 2-O-BENZYL-3,4-ISOPROPYLIDENE-D-ERYTHROSE; (R)-(+)-2-HYDROXY-1,2,2-TRIPHENYLETHYL ACETATE; STEREOSELECTIVE ALDOL REACTION OF DOUBLY DEPROTONATED 2-HYDROXY-1,2,2-TRIPHENYLETHYL ACETATE (HYTRA): (R)-3-HYDROXY-4-METHYLPENTENOIC ACID; (2S,4S)-2,4,5-TRIHYDROXY-PENTANOIC ACID 4,5-ACETONIDE METHYL ESTER; (1 R,5R)-(+)-VERBENONE OF HIGH OPTICAL PURITY; SYNTHESIS OF (S)-2-METHYL-PROLINE: A GENERAL METHOD FOR THE PREPARATION OF a-BRANCHED AMINO ACIDS; A...
2.53М, ENG.
Семьдесят первый номер брошюры «Органический синтез» содержит описания следующих соединений: ASYMMETRIC HYDROGENATION OF 3-OXO CARBOXYLATES USING BINAP-RUTHENIUM COMPLEXES: (R)-(-)-M ETHYL 3-H YD ROXYBUTANOATE; ASYMMETRIC CATALYTIC GLYOXYLATE-ENE REACTION: METHYL (2R)-2-HYDROXY-4-PHENYL-4-PENTENOATE; (1 R,2R)-(+)- AND (1 S,2S)-(-)-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE; ENANTIOSELECTIVE, CATALYTIC DIELS-ALDER REACTION: (1S-endo)-3-(BICYCLO[2.2.1]HEPT-5-EN-2-YLCARBONYL)-2-OXA-ZOLIDINONE; DIRECT DEGRADATION OF THE BIOPOLYMER POLY[(R)-3-HYDROXY-BUTYRIC ACID] TO (R)-3-HYDR0XY-BUTANOIC ACID AND ITS METHYL ESTER; (-)-(1S,4R)-CAMPHAN0YL CHLORIDE; 3-(S)-[(tert-BUTYLDIPHEIMYLSILYL)-0XY]-2-BUTAN0NE; STEREOCONTROLLED PREPARATION OF 3-ACYLTETRAHYDROFURANS FROM ACID-PROMOTED REARRANGEMENTS OF ALLYLIC KETALS:...
2.28М, ENG.
Семидесятый номер брошюры «Органический синтез» содержит описания следующих соединений: SYNTHESIS OF N-PROTECTED a-AMINO ACIDS FROM N-(BENZYLOXYCARBONYL)-L-SERINE VIA ITS 3-LACTONE: N-(BENZYLOXYCARBONYL)-i-(PYRAZOL-1-YL)-L-ALANINE; SYNTHESIS OF N-tert-BUTOXY-CARBONYL-L-SERINE LACTONE AND THE p-TOLUENESULFONIC ACID SALT OF (S)-3-AMINO-2-OXETANONE; 1,1-DIMETHYLETHYL (S)- OR (R)-4-FORMYL-2.2-DIMETHYL-3-OXAZOLI Dl N ECARBOXYLATE: A USEFUL SERINAL DERIVATIVE; N-(BENZYLOXYCARBONYL)-L-VINYLGLYCINE METHYL ESTER; (R)-(-)-10-METHYL-1(9)-OCTAL-2-ONE; (R,R)-1,2-DIPHENYL-l ,2-ETHANEDIOL (STILBENE DIOL); A STABLE CHIRAL 1,4-DIHYDRO-PYRIDINE EQUIVALENT FOR THE ASYMMETRIC SYNTHESIS OF SUBSTITUTED PIPERIDINES: 2-CYANO-6-PHENYLOXAZOLO-PIPERIDINE; (S)-(-)- AND (R)-(+)-1,1-BI-2-NAPHTHOL; 3,4-DIETHYLPYRROLE AN...
2.71М, ENG.
Шестьдесят девятый номер брошюры «Органический синтез» содержит описания следующих соединений: LIPASE-CATALYZED KINETIC RESOLUTION OF ALCOHOLS VIA CHLOROACETATE ESTERS: (-)-(1 R,2S)-trans-2-PHENYLCYCLO-HEXANOL AND (+)-(1S,2R)-trans-2-PHENYLCYCLOHEXANOL; ENANTIOMERICALLY PURE ETHYL (R)- AND (SJ-2-FLUORO-HEXANOATE BY ENZYME-CATALYZED KINETIC RESOLUTION; ENANTIOSELECTIVE SAPONIFICATION WITH PIG LIVER ESTERASE (PLE): (1S,2S,3R)- 3-HYDROXY-2-NITROCYCLOHEXYL ACETATE; DIASTEREOSELECTIVE FORMATION OF a-METHOXYCARBONYL LACTONES THROUGH AN INTRAMOLECULAR DIELS-ALDER REACTION: (4RS,4aRS,6RS,8aRS)-, (4S,4aS,6S,8aS)- AND (4R,4aR,6R,8aR)-4-METHOXY-CARBONYL-1,1,6-TRIMETHYL-1,4,4a,5,6,7,8,8a-OCTAHYDRO-2,3-BENZOPYRONE [rac-5, (+)-5, and (-)-5]; STEREOSELECTIVE 1,4-FUNCTIONAL-IZATIONS OF CONJUGATED DIENES: ...
2.96М, ENG.
Шестьдесят восьмой номер брошюры «Органический синтез» содержит описания следующих соединений: 1-TRIMETHYLSILYLDIA ZOMETHANE; (PHENYLTHIO)NITROMETHANE; REPARATION AND USE OF LITHIUM ACETYLIDE: 1-METHYL-2-ETHYNYL-endo-33-DIMETHYL-2-NORB0RNAN0L; ACETYLTRIMETHYLSILANE; 3-BUTYLCYCLOBUTENONE; VICINAL DICARBOXYLATION OF AN ALKENE: cis-l-METHYLCYCLO-PENTANE-1.2-DICARB0XYLIC ACID; ENANTIOSELECTIVE OXIDATION OF A SULFIDE: (S)-(-)-METHYL p-TOLYL SULFOXIDE; YEAST REDUCTION OF 2 ,2-DIMETHYL-CYCLOHEXANE-l ,3-DIONE : (S)-(+)-3-HYDROXY-2,2-DIMETHYL-CYCLOHEXANONE; DIRECTED HOMOGENEOUS HYDROGENATION: METHYL anti-3-HYDROXY-2-METHYLPENTANOATE; (S) -4-(PHENYLMETHYL)-2-0XA20LIDIN0NE; DIASTEREOSELECTIVE ALDOL CONDENSATION USING A CHIRAL OXAZOLIDINONE AUXILIARY: (2S*,3S*)-3-HYDR0XY-3-PHENYL-2-METHYLPROPANOIC ACI...
1.57М, ENG.
Шестьдесят седьмой номер брошюры «Органический синтез» содержит описания следующих соединений: 1,4-FUNCTIONALIZATION OF 1,3-DIENES VIA PALLADIUM-CATALYZED CHLORO-ACETOXYLATION AND ALLELIC AMINATION: 1-ACET0XY-4-DIETHYLAMIN0-2-BUTENE AND 1-ACET0XY-4-BENZYLAMIN0-2-BUTENE; PALLADIUM(O)-CATALYZED syn-1,4-ADDITION OF CARBOXYLIC ACIDS TO CYCLOPENTADIENE MONOEPOXIDE: cis-3-ACETOXY-5-HYDR0XYCYCL0PENT-1-ENE; 4,4-DIMETHYL-2-CYCL0PENTEN-l;0NE; a-DIPHENYLMETHYLSILYLATION OF ESTER ENOLATES: 2-METHYL-2-UNDECENE FROM ETHYL DECANOATE; N-BENZYL-N-METHOXYMETHYL-N-(TRIMETHYLSILYL)METHYLAMINE AS AN AZOMETHINE YLIDE EQUIVALENT: 2,6-DI0X0-l-PHENYL-4-BENZYL-l,4- DIAZABICYCLO[3.3.0]OCTANE; ALKYLATIONS USING HEXACARBONYL-(PROPARGYLIUM)DICOBALT SALTS: 2-(l-METHYL-2-PR0PYNYL)-CYCLOHEXANONE; ETHYNYL p-TOLYL SULFONE; ...
1.58М, ENG.
Шестьдесят шестой номер брошюры «Органический синтез» содержит описания следующих соединений: APROTIC DOUBLE MICHAEL ADDITION: PREPARATION OF 1,3-DIMETHYL-5-0X0BICYCL0[2.2.2]OCTANE-2-CARBOXYLIC ACID; COPPER-CATALYZED CONJUGATE ADDITION OF A ZINC HOMOENOLATE: LTHYL 3-[3-(TRIMETHYLSILYLOXY)CYCLOHEX-2-ENYL)]PR0PIONATE; CONJUGATE ADDITION/CYCLI ZATION OF A CYANOCUPRATE: 2-CAR BOMETHOXY-3-VINYLCYCLOPENTANONE; PALLADIUM-CATALYZED SYNTHESIS OF CONJUGATED OIENES: (5Z,7E)-5,7-HEXADECADIENE; SYNTHESIS OF BIARYLS VIA PALLADIUM-CROSS COUPLING: 2-METHYL-4'-NITROBIPHENYL; VINYL RADICAL CYCLI ZATION VIA ADDITION OF TIN RADICALS TO TRIPLE BONDS; CYCLOPENTANONES FROM CARBOXYLIC ACIDS VIA INTRAMOLECULAR ACYLATION OF ALKYLSILANES: 2-METHYL-2-VINYLCYCL0PENTAN0NE. И некоторые другие. Всего рассмотрено 28 соеди...
1.91М, ENG.
Шестьдесят пятый номер брошюры «Органический синтез» содержит описания следующих соединений: A GENERAL SYNTHETIC METHOD FOR THE PREPARATION OF CONJUGATED DIENES FROM OLEFINS USING BROMOMETHANESULFONYL BROMIDE: 1,2-DI METHYLENECYCLOHEXANE; PREPARATION AND INVERSE ELECTRON DEMAND DIELS-ALDER REACTION OF AN ELECTRON-DEFICIENT DIENE: METHYL 2-0X0-5,6,7.8-TETRAHYDR0-2H-1-BENZOPYRAN-3-CARB0XYLATE; AMBIENT TEMPERATURE ULLMANN REACTION: 4,5,4',5'-TETRAMETHOXY-1,Г-BIPHENYL-2,2'-DICARBOXALDEHYDE; GEMINAL ACYLATION-ALKYLATION AT A CARBONYL CENTER USING DIETHYL N-BENZYLIDENEAM1NOMETHYLPHOSPH0NATE: PREPARATION OF 2-METHYL-2-PHENYL-4-PENTENAL; 4-ACETOXYAZETIDIN-2-0NE: SYNTHESIS OF A KEY BETA-LACTAM INTERMEDIATE BY A [2 + 2] CYCLOADDITION ROUTE; 1,3-DI METHYL-3-METHOXY-4-PHENYL-AZETIDINONE. И некоторые д...
2.21М, ENG.
Шестьдесят четвертый номер брошюры «Органический синтез» содержит описания следующих соединений: ELECTROPHIL1С N-AMINATION OF IMIDE SODIUM SALTS WITH O-DIPHENYLPHOS-PHINYLHYDROXYLAMINE (DPH): 7-AMINOTHEOPHYLLINE; ETHYL 4-HYDR0XYCR0T0NATE; ETHYL ISOCROTONATE; FORMYL TRANSFER TO GRIGNARD REAGENTS: 3-PHENYLPROPIONALDEHYDE; a-HYDROXY KETONES FROM THE OXIDATION OF ENOL SILYL ETHERS WITH m-CHLOROPERBENZOIC ACID: 6-HYDROXY-3,5,5-TRIMETHYL-2-CYCLOHEXEN-I-ONE; HYDROXYLATION OF ENOLATES WITH OXODIPEROXYMOLYBDENUM(PYRIDINE)-(HEXAMETHYLPHOSPHOR1С TRIAMIDE), HoOr-PyHMPA (HoOPH): l,7,7-TRIMETHYL-3-HYDROXY-BICYCL0[2.2.1]HEPTAN-2-0NE. И некоторые другие. Всего рассмотрено 32 соединения.
1.76М, ENG.
Шестьдесят третий номер брошюры «Органический синтез» содержит описания следующих соединений: L-VALINOL; OPTICALLY ACTIVE EPOXIDES FROM VICINAL DIOLS VIA VICINAL ACETOXY BROMIDES: THE ENANTIOMERIC METHYLOXIRANES; CYCLOPROPANONE ETHYL HEMIACETAL FROM ETHYL 3-CHLOROPROPANOATE; HEXAFLUOROACETONE; tert-BUTOXYCARBONYLATION OF AMINO ACIDS AND THEIR DERIVATIVES: N-tert-BUTOXYCARBONYL-L-PHENYLALANINE; N-tert-BUTOXYCARBONYL-L-PHENYLALANINE; PEPTIDE SYNTHESIS USING l-(4-CHL0R0PHENYL)-3-(4'-METHYL-l'-PIPERAZINYL)-2-PR0PYN-1-0NE AS REAGENT: BENZYLOXYCARBONYL-L-ALANYL-L-CYSTEINE METHYL ESTER AND BENZYLOXYCARBONYL-L-ASPARTYL-Uert-BUTYL ESTER)-L-PHENYLALANYL-L-VALINE METHYL ESTER; ESTERIFICATION OF CARBOXYLIC ACIDS WITH DICYCL0HEXYLCARB0DIIMIDE-4-DIMETHYLAMINOPYRIDINE: tert-BUTYL ETHYL FUMARATE. И некото...
2.17М, ENG.
Шестьдесят второй номер брошюры «Органический синтез» содержит описания следующих соединений: Z-1-IODOHEXENE; A GENERAL SYNTHETIC METHOD FOR THE PREPARATION OF METHYL KETONES FROM TERMINAL OLEFINS: 2-DECANONE; (?)-ALKYL-(?),(?)-UNSATURATED ESTERS FROM ENOL PHOSPHATES OF (?)-KETO ESTERS: METHYL 2-METHYL-1-CYCLOHEXENE-1-CARBOXYLATE; THE C-ARYLATION OF (?)-DICARBONYL COMPOUNDS: ETHYL 1-p-METHOXYPHENYL)-2-OXOCYCLOHEXANECARBOXYLATE; PALLADIUM-CATALYZED SYNTHESIS OF 1,4-DIENES BY ALLYLATION OF ALKENYLALANES: (?)-FARNESENE; PALLADIUM-PHOSPHINE COMPLEX CATALYZED REACTION OF ORGANOLITHIUM COMPOUNDS AND ALKENYL HALIDES: (Z)-(?)[2-(N,N-DIMETHYLAMINO)PHENYL]-STYRENE; cis-N-TOSYL-3-METHYL-2-AZABICYCLO[3.3.0]OCT-3-ENE; SILYLATION OF 2-METHYL-2-PROPEN-1-OL DIANION: 2-(HYDROXYMETHYL)-ALLYLTRIMETHYLSILANE...
1.79М, ENG.
Шестьдесят первый номер брошюры «Органический синтез» содержит описания следующих соединений: ACID CHLORIDES FROM (?)-Кeто ACIDS WITH (?),(?)-DiCHLOROMETHYL METHYL ETHER: PYRUVOYL CHLORIDE; ALIPHATIC AND AROMATIC (?)-KETOESTERS FROM MONOETHYL MALONATE: ETHYL 2-BUTYRYLACETATE; PREPARATION OF 4-ALKYL- AND 4-HALOBENZOYL CHLORIDES: 4-PENTYLBENZOYL CHLORIDE; BENZYL ISOCYANIDE: OXIDATION OF 5-AMINOTETRAZOLES; BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE; SUBSTITUTED (?)-BUTYROLACTONES FROM CARBOXYLIC ACIDS AND OLEFINS: (?)-(n-OCTYL)-(?)-BUTYROLACTONE; CHIRAL MEDIA FOR ASYMMETRIC SOLVENT INDUCTIONS. (S,S-(+)-1,4-BIS(DIMETHYLAMINO)-2,3-DlMETHOXYBUTANE FROM (R,R)-(+)-TARTARIC ACID DIETHYL ESTER; CYANIC ACID ESTERS FROM PHENOLS: PHENYL CYANATE; 1,6-DIMETHYLTRICYCLO[4.1.0.0(?)]HEPT-3-ENE. И некоторые д...
2.25М, ENG.
Шестидесятый номер брошюры «Органический синтез» содержит описания следующих соединений: ANODIC OXIDATION OF ACIDS: DIMETHYL DECANEDIOATE; ATROPALDEHYDE; CARBOXYLIC ACIDS FROM THE OXIDATION OF TERMINAL ALKENES BY PERMANGANATE: NONADECANOIC ACID; CONVERSION OF KETONES то CYANOHYDRINS: BENZOPHENONE CYANOHYDRIN; 1,2-CYCLOBUTANEDIONE; CYCLOBUTANONE; CYCLOPROPANECARBOXALDEHYDE; DEOXYGENATION OF EPOXIDES WITH LOWER VALENT TUNGSTEN HALIDES: trans-CYCLODODECENE; 2,6-DI-tert-BUTYL-4-METHYLPYRIDINE; DIELS-ALDER REACTION OF 1,2,4,5-HEXATETRAENE: TETRAMETHYL [2.2]PARACYCLOPHANE-4,5,12,13-TETRACARBOXYLATE; N-(2,4-DlFORMYL-5-HYDROXYPHENYL) ACETAMIDE; 1,2-DlPHENYL-3-METHYLCYCLOPROPENE: PREPARATION OF CHLOROPHENYLDIAZIRINE AND THERMAL GENERATION OF CHLOROPHENYLCARBENE. И некоторые другие. Всего рассмотрен...
1.83М, ENG.