Cyclic Voltammetry: Simulation and Analysis of Reaction Mechanisms
| Автор(ы): | Gosser D. K., Jr.
06.10.2007
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| Год изд.: | 1993 |
| Описание: | Cyclic voltammetry (CV) has been in the forefront of the study of electron transfer and its consequences. With the cyclic voltammetric method one can simultaneously activate molecules by electron transfer and probe subsequent chemical reactions. The cyclic voltammetric response curve thus provides information about electron transfer kinetics and thermodynamics as well as the consequences of electron transfer. This book introduces cyclic voltammetry and its application to the analysis of electrochemical reaction mechanisms. It also provides the experimentalist with a simulation-based approach for the analysis of cyclic voltammograms. |
| Оглавление: |
Обложка книги.
1.1 The Reduction Potential [1] 1.2 Electrode Kinetics [12] References [24] 2. The Cyclic Voltammetric Experiment [27] 2.1 An Overview [28] 2.2 The Electrochemical Cell [30] 2.3 Electrochemical Mechanisms: E&C Notation [35] 2.4 Distortions of the Faradaic Response [56] 2.5 Microelectrodes and Fast Scan Voltammetry [59] 2.6 Potential Step Methods and Cyclic Voltammetry [60] 2.7 Construction of a Fast Potentiostat [64] 2.8 Determination of the Number of Electrons [68] References [68] 3. A Survey of Electrochemical Mechanisms [71] 3.1 The CE Mechanism [72] 3.2 Multielectron Transfer [75] 3.3 Protonations at Equilibrium [77] 3.4 Catalytic Mechanisms [80] 3.5 The Reduction of Nitrobenzoic Acid [89] 3.6 Reduction of the Nit'rosonium Cation and Its Complexes [92] 3.7 Reactivity of 17-, 18-, and 19-Electron Tungsten Complexes [95] 3.8 Mechanisms Involving Adsorption [97] References [102] 4. The Simulation of Electrochemical Experiments [105] 4.1 The Discretized Diffusion Equation [105] 4.2 Evaluation of the Boundary Conditions [108] 4.3 Dimensionless Units [109] 4.4 Solution Chemical Kinetics [110] 4.5 A Sample Simulation Program [110] References [114] 5. CVSIM: A General Program for the Simulation of Cyclic Voltammetry Experiments [115] 5.1 An Overview of CVSIM [115] 5.2 Extensions of the Simulation Method [117] 5.3 Accuracy of Simulations [120] 5.4 Installation and Use of CVSIM and CVGRAF [123] 5.5 Examples [125] References [135] 6. CVFIT: Simplex Data Analysis with CVSIM [137] 6.1 CVFIT: Simplex Data Analysis with CVSIM [137] 6.2 Instructions for the use of CVFIT [138] 6.3 A Prototype Analysis: The EC Mechanism [139] 6.4 Some Final Comments on Simulation Analysis [145] References [148] Appendix: Summary of Instructions for CVSIM, CVGRAF, CVFIT, and DSTEP [149] Index [153] |
| Формат: | djvu + ocr |
| Размер: | 8600934 байт |
| Язык: | ENG |
| Рейтинг: |
174
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| Открыть: | Ссылка (RU) |